{"created":"2023-06-19T12:09:03.554490+00:00","id":15624,"links":{},"metadata":{"_buckets":{"deposit":"fd44d081-eb33-4f5c-85aa-36eac483f8e7"},"_deposit":{"created_by":17,"id":"15624","owners":[17],"pid":{"revision_id":0,"type":"depid","value":"15624"},"status":"published"},"_oai":{"id":"oai:kokushikan.repo.nii.ac.jp:00015624","sets":["928:38:39:1333"]},"author_link":["25048","25049"],"item_10002_biblio_info_168":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-03-31","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"21","bibliographicPageStart":"9","bibliographicVolumeNumber":"15","bibliographic_titles":[{"bibliographic_title":"国士舘大学理工学部紀要"},{"bibliographic_title":"TRANSACTIONS OF THE KOKUSHIKAN UNIVERSITY SCHOOL OF SCIENCE AND ENGINEERING","bibliographic_titleLang":"en"}]}]},"item_10002_description_151":{"attribute_name":"著者ID","attribute_value_mlt":[{"subitem_description":"　","subitem_description_type":"Other"},{"subitem_description":"J-GLOBAL ID : 200901085417108282","subitem_description_type":"Other"}]},"item_10002_description_161":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"　The reaction rate constant is defined as the rate at which a reactant annihilates or a product creates in a chemical reaction. The Hamiltonian of the reaction system describing elementary reactions has already been formulated by Miller et al（J. Chem. Phys. 1980, 72, 99-112） In addition, the reaction coordinates representing the progress of the reaction are also formulated by Fukui.（J. Phys. Chem. 1970, 74, 4161-4163） In the present paper, on the basis of these two theories, we first formulated the reaction rate constants of elementary reactions using classical statistical mechanics. Then we rewrited the rate constans quantum-mechanically according to the method of Wigner representations. By this rewriting, a correction term representing the quantum effect of the reaction rate constant was naturally derived.","subitem_description_type":"Abstract"}]},"item_10002_description_175":{"attribute_name":"論文ID(CRID)","attribute_value_mlt":[{"subitem_description":"1520574190701913856","subitem_description_type":"Other"}]},"item_10002_description_180":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10002_heading_148":{"attribute_name":"見出し","attribute_value_mlt":[{"subitem_heading_banner_headline":"論文","subitem_heading_language":"ja"},{"subitem_heading_banner_headline":"Original Papers","subitem_heading_language":"en"}]},"item_10002_publisher_169":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"国士舘大学理工学部"}]},"item_10002_source_id_170":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1882-4013","subitem_source_identifier_type":"PISSN"}]},"item_10002_source_id_172":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA12316266","subitem_source_identifier_type":"NCID"}]},"item_10002_subject_177":{"attribute_name":"NDC","attribute_value_mlt":[{"subitem_subject":"431.3","subitem_subject_scheme":"NDC"},{"subitem_subject":"431.34","subitem_subject_scheme":"NDC"}]},"item_10002_version_type_181":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"梅崎, 馨章","creatorNameLang":"ja"},{"creatorName":"ウメサキ, ケイショウ","creatorNameLang":"ja-Kana"},{"creatorName":"Umesaki, Keisho","creatorNameLang":"en"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{"nameIdentifier":"25048","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"小田井, 圭","creatorNameLang":"ja"},{"creatorName":"オダイ, ケイ","creatorNameLang":"ja-Kana"},{"creatorName":"Odai, Kei","creatorNameLang":"en"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{"nameIdentifier":"25049","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-10-29"}],"displaytype":"detail","filename":"1882_4013_015_03.pdf","filesize":[{"value":"1.3 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文","url":"https://kokushikan.repo.nii.ac.jp/record/15624/files/1882_4013_015_03.pdf"},"version_id":"5424836c-5bb3-4a1b-b01d-c3b6fc43af51"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"reaction coordinates","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"reaction rate constants","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Wigner representation","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"反応速度定数の量子論的定式化 : Wigner表示","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"反応速度定数の量子論的定式化 : Wigner表示","subitem_title_language":"ja"},{"subitem_title":"A quantum mechanical formulation of reaction rate constants : Wigner representation","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"17","path":["1333"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2022-10-29"},"publish_date":"2022-10-29","publish_status":"0","recid":"15624","relation_version_is_last":true,"title":["反応速度定数の量子論的定式化 : Wigner表示"],"weko_creator_id":"17","weko_shared_id":-1},"updated":"2024-04-14T06:25:52.396352+00:00"}