@article{oai:kokushikan.repo.nii.ac.jp:00015624,
 author = {梅崎, 馨章 and Umesaki, Keisho and 小田井, 圭 and Odai, Kei},
 journal = {国士舘大学理工学部紀要, TRANSACTIONS OF THE KOKUSHIKAN UNIVERSITY SCHOOL OF SCIENCE AND ENGINEERING},
 month = {Mar},
 note = {J-GLOBAL ID : 200901085417108282, The reaction rate constant is defined as the rate at which a reactant annihilates or a product creates in a chemical reaction. The Hamiltonian of the reaction system describing elementary reactions has already been formulated by Miller et al（J. Chem. Phys. 1980, 72, 99-112） In addition, the reaction coordinates representing the progress of the reaction are also formulated by Fukui.（J. Phys. Chem. 1970, 74, 4161-4163） In the present paper, on the basis of these two theories, we first formulated the reaction rate constants of elementary reactions using classical statistical mechanics. Then we rewrited the rate constans quantum-mechanically according to the method of Wigner representations. By this rewriting, a correction term representing the quantum effect of the reaction rate constant was naturally derived., 1520574190701913856, application/pdf},
 pages = {9--21},
 title = {反応速度定数の量子論的定式化 : Wigner表示},
 volume = {15},
 year = {2022},
 yomi = {ウメサキ, ケイショウ and オダイ, ケイ}
}